Dispersion Energy Enforced Dimerization of a Cyclic Disilylated Plumbylene

[Image: see text] By reaction of 1,4-dipotassio-1,1,4,4-tetrakis(trimethylsilyl)tetramethyltetrasilane with PbBr(2) in the presence of triethylphosphine a base adduct of a cyclic disilylated plumbylene could be obtained. Phosphine abstraction with B(C(6)F(5))(3) led to formation of a base-free plumb...

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Detalles Bibliográficos
Autores principales: Arp, Henning, Baumgartner, Judith, Marschner, Christoph, Zark, Patrick, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2012
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3336735/
https://www.ncbi.nlm.nih.gov/pubmed/22455750
http://dx.doi.org/10.1021/ja300654t

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3336735/
https://www.ncbi.nlm.nih.gov/pubmed/22455750
http://dx.doi.org/10.1021/ja300654t

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