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First enantioseparation and circular dichroism spectra of Au(38) clusters protected by achiral ligands

Bestowing chirality to metals is central in fields such as heterogeneous catalysis and modern optics. Although the bulk phase of metals is symmetric, their surfaces can become chiral through adsorption of molecules. Interestingly, even achiral molecules can lead to locally chiral, though globally ra...

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Detalles Bibliográficos
Autores principales: Dolamic, Igor, Knoppe, Stefan, Dass, Amala, Bürgi, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Pub. Group 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3337976/
https://www.ncbi.nlm.nih.gov/pubmed/22531183
http://dx.doi.org/10.1038/ncomms1802