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First enantioseparation and circular dichroism spectra of Au(38) clusters protected by achiral ligands
Bestowing chirality to metals is central in fields such as heterogeneous catalysis and modern optics. Although the bulk phase of metals is symmetric, their surfaces can become chiral through adsorption of molecules. Interestingly, even achiral molecules can lead to locally chiral, though globally ra...
Autores principales: | Dolamic, Igor, Knoppe, Stefan, Dass, Amala, Bürgi, Thomas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Pub. Group
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3337976/ https://www.ncbi.nlm.nih.gov/pubmed/22531183 http://dx.doi.org/10.1038/ncomms1802 |
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