cis-Bis[(4-nitro­phen­yl)cyanamido-κN (1)]bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate

In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa­hedral geometry and is chelated by two phenanthroline ligands and two phenyl­cyanamide groups which occupy cis positions. The (4-nitro­phen­yl)cyanamide anions act...

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Autores principales: Chiniforoshan, Hossein, Jazestani, Mehdi, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343823/
https://www.ncbi.nlm.nih.gov/pubmed/22589797
http://dx.doi.org/10.1107/S1600536812009890
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author Chiniforoshan, Hossein
Jazestani, Mehdi
Notash, Behrouz
author_facet Chiniforoshan, Hossein
Jazestani, Mehdi
Notash, Behrouz
author_sort Chiniforoshan, Hossein
collection PubMed
description In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa­hedral geometry and is chelated by two phenanthroline ligands and two phenyl­cyanamide groups which occupy cis positions. The (4-nitro­phen­yl)cyanamide anions act as monodentate ligands. There is one classical inter­molecular O—H⋯N hydrogen bond and several C—H⋯O hydrogen bonds are also observed.
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spelling pubmed-33438232012-05-15 cis-Bis[(4-nitro­phen­yl)cyanamido-κN (1)]bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate Chiniforoshan, Hossein Jazestani, Mehdi Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa­hedral geometry and is chelated by two phenanthroline ligands and two phenyl­cyanamide groups which occupy cis positions. The (4-nitro­phen­yl)cyanamide anions act as monodentate ligands. There is one classical inter­molecular O—H⋯N hydrogen bond and several C—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343823/ /pubmed/22589797 http://dx.doi.org/10.1107/S1600536812009890 Text en © Chiniforoshan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiniforoshan, Hossein
Jazestani, Mehdi
Notash, Behrouz
cis-Bis[(4-nitro­phen­yl)cyanamido-κN (1)]bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate
title cis-Bis[(4-nitro­phen­yl)cyanamido-κN (1)]bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate
title_full cis-Bis[(4-nitro­phen­yl)cyanamido-κN (1)]bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate
title_fullStr cis-Bis[(4-nitro­phen­yl)cyanamido-κN (1)]bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate
title_full_unstemmed cis-Bis[(4-nitro­phen­yl)cyanamido-κN (1)]bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate
title_short cis-Bis[(4-nitro­phen­yl)cyanamido-κN (1)]bis­(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate
title_sort cis-bis[(4-nitro­phen­yl)cyanamido-κn (1)]bis­(1,10-phenanthroline-κ(2) n,n′)nickel(ii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343823/
https://www.ncbi.nlm.nih.gov/pubmed/22589797
http://dx.doi.org/10.1107/S1600536812009890
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