cis-Bis[(4-nitrophenyl)cyanamido-κN (1)]bis(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate
In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octahedral geometry and is chelated by two phenanthroline ligands and two phenylcyanamide groups which occupy cis positions. The (4-nitrophenyl)cyanamide anions act...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343823/ https://www.ncbi.nlm.nih.gov/pubmed/22589797 http://dx.doi.org/10.1107/S1600536812009890 |
_version_ | 1782231852691488768 |
---|---|
author | Chiniforoshan, Hossein Jazestani, Mehdi Notash, Behrouz |
author_facet | Chiniforoshan, Hossein Jazestani, Mehdi Notash, Behrouz |
author_sort | Chiniforoshan, Hossein |
collection | PubMed |
description | In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octahedral geometry and is chelated by two phenanthroline ligands and two phenylcyanamide groups which occupy cis positions. The (4-nitrophenyl)cyanamide anions act as monodentate ligands. There is one classical intermolecular O—H⋯N hydrogen bond and several C—H⋯O hydrogen bonds are also observed. |
format | Online Article Text |
id | pubmed-3343823 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33438232012-05-15 cis-Bis[(4-nitrophenyl)cyanamido-κN (1)]bis(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate Chiniforoshan, Hossein Jazestani, Mehdi Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octahedral geometry and is chelated by two phenanthroline ligands and two phenylcyanamide groups which occupy cis positions. The (4-nitrophenyl)cyanamide anions act as monodentate ligands. There is one classical intermolecular O—H⋯N hydrogen bond and several C—H⋯O hydrogen bonds are also observed. International Union of Crystallography 2012-03-14 /pmc/articles/PMC3343823/ /pubmed/22589797 http://dx.doi.org/10.1107/S1600536812009890 Text en © Chiniforoshan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chiniforoshan, Hossein Jazestani, Mehdi Notash, Behrouz cis-Bis[(4-nitrophenyl)cyanamido-κN (1)]bis(1,10-phenanthroline-κ(2) N,N′)nickel(II) methanol monosolvate |
title |
cis-Bis[(4-nitrophenyl)cyanamido-κN
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) methanol monosolvate |
title_full |
cis-Bis[(4-nitrophenyl)cyanamido-κN
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) methanol monosolvate |
title_fullStr |
cis-Bis[(4-nitrophenyl)cyanamido-κN
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) methanol monosolvate |
title_full_unstemmed |
cis-Bis[(4-nitrophenyl)cyanamido-κN
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) methanol monosolvate |
title_short |
cis-Bis[(4-nitrophenyl)cyanamido-κN
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)nickel(II) methanol monosolvate |
title_sort | cis-bis[(4-nitrophenyl)cyanamido-κn
(1)]bis(1,10-phenanthroline-κ(2)
n,n′)nickel(ii) methanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343823/ https://www.ncbi.nlm.nih.gov/pubmed/22589797 http://dx.doi.org/10.1107/S1600536812009890 |
work_keys_str_mv | AT chiniforoshanhossein cisbis4nitrophenylcyanamidokn1bis110phenanthrolinek2nnnickeliimethanolmonosolvate AT jazestanimehdi cisbis4nitrophenylcyanamidokn1bis110phenanthrolinek2nnnickeliimethanolmonosolvate AT notashbehrouz cisbis4nitrophenylcyanamidokn1bis110phenanthrolinek2nnnickeliimethanolmonosolvate |