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cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2λ(5)-dioxaphospholan-2-yloxy)butan-2-olato-κ(2) O,P]oxido(triphenylphosphane-κP)rhenium(V)
The title compound, cis-[Re(C(12)H(24)O(4)P)Cl(2)O(C(18)H(15)P)], was prepared from the analogous trans isomer [Głowiak et al. (2000 ▶). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The Re(V) atom adopts a distorted octahedral coordination geometry. Besides being coordinated by...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344344/ https://www.ncbi.nlm.nih.gov/pubmed/22590110 http://dx.doi.org/10.1107/S1600536812015565 |