cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V)

The title compound, cis-[Re(C(12)H(24)O(4)P)Cl(2)O(C(18)H(15)P)], was prepared from the analogous trans isomer [Głowiak et al. (2000 ▶). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The Re(V) atom adopts a distorted octa­hedral coordination geometry. Besides being coordinated by...

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Autores principales: Skarżyńska, Anna, Siczek, Miłosz, Gniewek, Andrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344344/
https://www.ncbi.nlm.nih.gov/pubmed/22590110
http://dx.doi.org/10.1107/S1600536812015565
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author Skarżyńska, Anna
Siczek, Miłosz
Gniewek, Andrzej
author_facet Skarżyńska, Anna
Siczek, Miłosz
Gniewek, Andrzej
author_sort Skarżyńska, Anna
collection PubMed
description The title compound, cis-[Re(C(12)H(24)O(4)P)Cl(2)O(C(18)H(15)P)], was prepared from the analogous trans isomer [Głowiak et al. (2000 ▶). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The Re(V) atom adopts a distorted octa­hedral coordination geometry. Besides being coordinated by the oxide and the butano­late O atoms, the Re(V) atom is coordinated by a pair of chloride ligands and two P atoms in cis positions with respect to each other. In the crystal, adjacent mol­ecules are linked by weak C—H⋯Cl inter­actions, forming a three-dimensional network.
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spelling pubmed-33443442012-05-15 cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V) Skarżyńska, Anna Siczek, Miłosz Gniewek, Andrzej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, cis-[Re(C(12)H(24)O(4)P)Cl(2)O(C(18)H(15)P)], was prepared from the analogous trans isomer [Głowiak et al. (2000 ▶). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The Re(V) atom adopts a distorted octa­hedral coordination geometry. Besides being coordinated by the oxide and the butano­late O atoms, the Re(V) atom is coordinated by a pair of chloride ligands and two P atoms in cis positions with respect to each other. In the crystal, adjacent mol­ecules are linked by weak C—H⋯Cl inter­actions, forming a three-dimensional network. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344344/ /pubmed/22590110 http://dx.doi.org/10.1107/S1600536812015565 Text en © Skarżyńska et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Skarżyńska, Anna
Siczek, Miłosz
Gniewek, Andrzej
cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V)
title cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V)
title_full cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V)
title_fullStr cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V)
title_full_unstemmed cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V)
title_short cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V)
title_sort cis-dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) o,p]oxido(triphenyl­phosphane-κp)rhenium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344344/
https://www.ncbi.nlm.nih.gov/pubmed/22590110
http://dx.doi.org/10.1107/S1600536812015565
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AT gniewekandrzej cisdichlorido23dimethyl34455tetramethyl132l5dioxaphospholan2yloxybutan2olatok2opoxidotriphenylphosphanekprheniumv

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