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cis-Dichlorido[2,3-dimethyl-3-(4,4,5,5-tetra­methyl-1,3,2λ(5)-dioxaphospho­lan-2-yl­oxy)butan-2-olato-κ(2) O,P]oxido(triphenyl­phosphane-κP)rhenium(V)

The title compound, cis-[Re(C(12)H(24)O(4)P)Cl(2)O(C(18)H(15)P)], was prepared from the analogous trans isomer [Głowiak et al. (2000 ▶). Polyhedron, 19, 2667–2672] by a trans–cis isomerization reaction. The Re(V) atom adopts a distorted octa­hedral coordination geometry. Besides being coordinated by...

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Detalles Bibliográficos
Autores principales: Skarżyńska, Anna, Siczek, Miłosz, Gniewek, Andrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344344/
https://www.ncbi.nlm.nih.gov/pubmed/22590110
http://dx.doi.org/10.1107/S1600536812015565

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