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Kinetic Analysis for Macrocyclizations Involving Anionic Template at the Transition State

Several kinetic models for the macrocyclization of a C(2) pseudopeptide with a dihalide through a S(N)2 reaction have been developed. These models not only focus on the kinetic analysis of the main macrocyclization reaction, but also consider the competitive oligomerization/polymerization processes...

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Detalles Bibliográficos
Autores principales: Martí-Centelles, Vicente, Burguete, M. Isabel, Luis, Santiago V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Scientific World Journal 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3347868/
https://www.ncbi.nlm.nih.gov/pubmed/22666148
http://dx.doi.org/10.1100/2012/748251