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Synthesis of Oligosilanyl Compounds of Group 4 Metallocenes with the Oxidation State +3

[Image: see text] Recently, we showed that titanocene silyls are much more stable with Ti in the oxidation state +3. The current study demonstrates that analogous Zr and Hf compounds can also be obtained by reaction of a suitable metalate precursor with an oligosilanyl dianion. As the obtained compl...

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Detalles Bibliográficos
Autores principales: Arp, Henning, Zirngast, Michaela, Marschner, Christoph, Baumgartner, Judith, Rasmussen, Kenneth, Zark, Patrick, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2012
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3377365/
https://www.ncbi.nlm.nih.gov/pubmed/22723723
http://dx.doi.org/10.1021/om3001873