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Synthesis of Oligosilanyl Compounds of Group 4 Metallocenes with the Oxidation State +3
[Image: see text] Recently, we showed that titanocene silyls are much more stable with Ti in the oxidation state +3. The current study demonstrates that analogous Zr and Hf compounds can also be obtained by reaction of a suitable metalate precursor with an oligosilanyl dianion. As the obtained compl...
Autores principales: | Arp, Henning, Zirngast, Michaela, Marschner, Christoph, Baumgartner, Judith, Rasmussen, Kenneth, Zark, Patrick, Müller, Thomas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2012
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3377365/ https://www.ncbi.nlm.nih.gov/pubmed/22723723 http://dx.doi.org/10.1021/om3001873 |
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