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Sonogashira–Hagihara reactions of halogenated glycals

Herein, we report on our findings of the Sonogashira–Hagihara reaction with 1-iodinated and 2-brominated glycals using several aromatic and aliphatic alkynes. This Pd-catalyzed cross-coupling reaction presents a facile access to alkynyl C-glycosides and sets the stage for a reductive/oxidative refun...

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Detalles Bibliográficos
Autores principales: Koester, Dennis C, Werz, Daniel B
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3388853/
https://www.ncbi.nlm.nih.gov/pubmed/23015813
http://dx.doi.org/10.3762/bjoc.8.75