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On the bromination of the dihydroazulene/vinylheptafulvene photo-/thermoswitch

Background: The dihydroazulene (DHA)/vinylheptafulvene (VHF) system (with two cyano groups at C1) functions as a photo-/thermoswitch. Direct ionic bromination of DHA has previously furnished a regioselective route to a 7,8-dibromide, which by elimination was converted to a 7-bromo-substituted DHA. T...

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Detalles Bibliográficos
Autores principales: Mazzanti, Virginia, Cacciarini, Martina, Broman, Søren L, Parker, Christian R, Schau-Magnussen, Magnus, Bond, Andrew D, Nielsen, Mogens B
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3388886/
https://www.ncbi.nlm.nih.gov/pubmed/23015846
http://dx.doi.org/10.3762/bjoc.8.108