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Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate

In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the aryl­imido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N—C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group,...

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Detalles Bibliográficos
Autores principales: Wang, Manxiang, Tao, Shikai, Guo, Jing, Hao, Jian, Li, Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393191/
https://www.ncbi.nlm.nih.gov/pubmed/22807759
http://dx.doi.org/10.1107/S1600536812026323