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Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate

In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the aryl­imido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N—C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group,...

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Autores principales: Wang, Manxiang, Tao, Shikai, Guo, Jing, Hao, Jian, Li, Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393191/
https://www.ncbi.nlm.nih.gov/pubmed/22807759
http://dx.doi.org/10.1107/S1600536812026323
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author Wang, Manxiang
Tao, Shikai
Guo, Jing
Hao, Jian
Li, Qiang
author_facet Wang, Manxiang
Tao, Shikai
Guo, Jing
Hao, Jian
Li, Qiang
author_sort Wang, Manxiang
collection PubMed
description In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the aryl­imido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N—C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group, and is typical for the imido monodentate behaviour described in analogous hybrids. Light components of the structure are extensively disordered. The aryl ester group is disordered over two positions with occupancies refined to 0.559 (3) and 0.441 (3). Both independent tetra­butyl­ammonium cations have butyl chains partially split over two sites, with occupancies as in the aryl group of the anion. Finally, the ether solvent mol­ecule is disordered around an inversion centre. In the crystal, cations and anions inter­act via C—H⋯O contacts, involving O atoms of the polyoxidometalate anion and the ester group of the aryl­imido ligand as acceptor groups.
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spelling pubmed-33931912012-07-17 Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate Wang, Manxiang Tao, Shikai Guo, Jing Hao, Jian Li, Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the aryl­imido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N—C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group, and is typical for the imido monodentate behaviour described in analogous hybrids. Light components of the structure are extensively disordered. The aryl ester group is disordered over two positions with occupancies refined to 0.559 (3) and 0.441 (3). Both independent tetra­butyl­ammonium cations have butyl chains partially split over two sites, with occupancies as in the aryl group of the anion. Finally, the ether solvent mol­ecule is disordered around an inversion centre. In the crystal, cations and anions inter­act via C—H⋯O contacts, involving O atoms of the polyoxidometalate anion and the ester group of the aryl­imido ligand as acceptor groups. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393191/ /pubmed/22807759 http://dx.doi.org/10.1107/S1600536812026323 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Manxiang
Tao, Shikai
Guo, Jing
Hao, Jian
Li, Qiang
Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate
title Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate
title_full Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate
title_fullStr Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate
title_full_unstemmed Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate
title_short Bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate
title_sort bis(tetra­butyl­ammonium) [2-(eth­oxy­carbony)phenyl­imido]-μ(6)-oxido-dodeca-μ(2)-oxido-penta­oxidohexa­molybdenum diethyl ether hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393191/
https://www.ncbi.nlm.nih.gov/pubmed/22807759
http://dx.doi.org/10.1107/S1600536812026323
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