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Bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate
In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the arylimido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N—C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393191/ https://www.ncbi.nlm.nih.gov/pubmed/22807759 http://dx.doi.org/10.1107/S1600536812026323 |
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author | Wang, Manxiang Tao, Shikai Guo, Jing Hao, Jian Li, Qiang |
author_facet | Wang, Manxiang Tao, Shikai Guo, Jing Hao, Jian Li, Qiang |
author_sort | Wang, Manxiang |
collection | PubMed |
description | In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the arylimido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N—C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group, and is typical for the imido monodentate behaviour described in analogous hybrids. Light components of the structure are extensively disordered. The aryl ester group is disordered over two positions with occupancies refined to 0.559 (3) and 0.441 (3). Both independent tetrabutylammonium cations have butyl chains partially split over two sites, with occupancies as in the aryl group of the anion. Finally, the ether solvent molecule is disordered around an inversion centre. In the crystal, cations and anions interact via C—H⋯O contacts, involving O atoms of the polyoxidometalate anion and the ester group of the arylimido ligand as acceptor groups. |
format | Online Article Text |
id | pubmed-3393191 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931912012-07-17 Bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate Wang, Manxiang Tao, Shikai Guo, Jing Hao, Jian Li, Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [(C(4)H(9))(4)N](2)[Mo(6)O(18)(C(9)H(9)NO(2))]·0.5C(4)H(10)O, the arylimido ligand is linked to an Mo atom of the Lindqvist-type polyoxidometalate anion by an Mo N bond of 1.726 (4) Å. The Mo N—C angles are 160.7 (5) and 167.6(5)° because of disorder affecting the aryl group, and is typical for the imido monodentate behaviour described in analogous hybrids. Light components of the structure are extensively disordered. The aryl ester group is disordered over two positions with occupancies refined to 0.559 (3) and 0.441 (3). Both independent tetrabutylammonium cations have butyl chains partially split over two sites, with occupancies as in the aryl group of the anion. Finally, the ether solvent molecule is disordered around an inversion centre. In the crystal, cations and anions interact via C—H⋯O contacts, involving O atoms of the polyoxidometalate anion and the ester group of the arylimido ligand as acceptor groups. International Union of Crystallography 2012-06-16 /pmc/articles/PMC3393191/ /pubmed/22807759 http://dx.doi.org/10.1107/S1600536812026323 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Manxiang Tao, Shikai Guo, Jing Hao, Jian Li, Qiang Bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate |
title | Bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate |
title_full | Bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate |
title_fullStr | Bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate |
title_full_unstemmed | Bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate |
title_short | Bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate |
title_sort | bis(tetrabutylammonium) [2-(ethoxycarbony)phenylimido]-μ(6)-oxido-dodeca-μ(2)-oxido-pentaoxidohexamolybdenum diethyl ether hemisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393191/ https://www.ncbi.nlm.nih.gov/pubmed/22807759 http://dx.doi.org/10.1107/S1600536812026323 |
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