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(E)-4-Amino-N′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide

The asymmetric unit of the title compound, C(15)H(15)N(3)O(2), comprises two crystallographically independent mol­ecules (A and B), each having an E conformation around the C=N bond. In each mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond making an S(6) ring motif. The dihedral angles bet...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393987/
https://www.ncbi.nlm.nih.gov/pubmed/22798852
http://dx.doi.org/10.1107/S1600536812027948
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author Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description The asymmetric unit of the title compound, C(15)H(15)N(3)O(2), comprises two crystallographically independent mol­ecules (A and B), each having an E conformation around the C=N bond. In each mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond making an S(6) ring motif. The dihedral angles between the substituted phenyl rings are 17.49 (9) and 10.03 (9)°. In the crystal, N—H⋯O hydrogen bonds link neighbouring independent mol­ecules into infinite chains, of the type –A–B–A–B–, along the a axis, enclosing R (2) (1)(7) ring motifs. The chains are linked by N—H⋯O hydrogen bonds and C—H⋯O inter­actions, leading to the formation of a three-dimensional network.
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spelling pubmed-33939872012-07-13 (E)-4-Amino-N′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(15)H(15)N(3)O(2), comprises two crystallographically independent mol­ecules (A and B), each having an E conformation around the C=N bond. In each mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond making an S(6) ring motif. The dihedral angles between the substituted phenyl rings are 17.49 (9) and 10.03 (9)°. In the crystal, N—H⋯O hydrogen bonds link neighbouring independent mol­ecules into infinite chains, of the type –A–B–A–B–, along the a axis, enclosing R (2) (1)(7) ring motifs. The chains are linked by N—H⋯O hydrogen bonds and C—H⋯O inter­actions, leading to the formation of a three-dimensional network. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393987/ /pubmed/22798852 http://dx.doi.org/10.1107/S1600536812027948 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
(E)-4-Amino-N′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide
title (E)-4-Amino-N′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide
title_full (E)-4-Amino-N′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide
title_fullStr (E)-4-Amino-N′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide
title_full_unstemmed (E)-4-Amino-N′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide
title_short (E)-4-Amino-N′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide
title_sort (e)-4-amino-n′-(2-hy­droxy-5-methyl­benzyl­idene)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393987/
https://www.ncbi.nlm.nih.gov/pubmed/22798852
http://dx.doi.org/10.1107/S1600536812027948
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