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Osmium(IV) complexes with 1H- and 2H-indazoles: Tautomer identity versus spectroscopic properties and antiproliferative activity

A one-pot synthesis of osmium(IV) complexes with two different tautomers of indazole, 1H-indazole and 2H-indazole, namely (H(2)ind)[Os(IV)Cl(5)(2H-ind)] (1) and (H(2)ind)[Os(IV)Cl(5)(1H-ind)] (2) is reported. Both compounds have been comprehensively characterized by NMR spectroscopy, ESI (electrospr...

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Detalles Bibliográficos
Autores principales: Büchel, Gabriel E., Stepanenko, Iryna N., Hejl, Michaela, Jakupec, Michael A., Keppler, Bernhard K., Heffeter, Petra, Berger, Walter, Arion, Vladimir B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3400055/
https://www.ncbi.nlm.nih.gov/pubmed/22687494
http://dx.doi.org/10.1016/j.jinorgbio.2012.04.001