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(13)C NMR Reveals No Evidence of n−π* Interactions in Proteins

An [Image: see text] interaction between neighboring carbonyl groups has been postulated to stabilize protein structures. Such an interaction would affect the [Image: see text]C chemical shielding of the carbonyl groups, whose paramagnetic component is dominated by [Image: see text] and [Image: see...

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Detalles Bibliográficos
Autores principales: Worley, Bradley, Richard, Georgia, Harbison, Gerard S., Powers, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3410932/
https://www.ncbi.nlm.nih.gov/pubmed/22876300
http://dx.doi.org/10.1371/journal.pone.0042075