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Asymmetric hydrogenation of ketones: Tactics to achieve high reactivity, enantioselectivity, and wide scope
Ru complexes with chiral diphosphines and amine-based ligands achieve high catalytic activity and enantioselectivity for the hydrogenation of ketones under neutral to slightly basic conditions. The chiral environment is controllable by changing the combination of these two ligands. A concerted six-m...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Japan Academy
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3417846/ https://www.ncbi.nlm.nih.gov/pubmed/20228621 http://dx.doi.org/10.2183/pjab.86.202 |