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[μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)]

The title compound, [Ru(2)(C(22)H(34)Si(2))(CO)(4)], contains two Ru(I) atoms linked by a bridging (η(5)-(t)BuC(5)H(2))(2)(SiMe(2))(2) ligand ((t)Bu is a tert-butyl and Me is a methyl group) with an Ru—Ru bond length of 2.8401 (7) Å. The dihedral angle between the planes of the cyclo­penta­dienyl ri...

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Detalles Bibliográficos
Autor principal: Zhu, Bolin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435588/
https://www.ncbi.nlm.nih.gov/pubmed/22969461
http://dx.doi.org/10.1107/S1600536812033454