[μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)]

The title compound, [Ru(2)(C(22)H(34)Si(2))(CO)(4)], contains two Ru(I) atoms linked by a bridging (η(5)-(t)BuC(5)H(2))(2)(SiMe(2))(2) ligand ((t)Bu is a tert-butyl and Me is a methyl group) with an Ru—Ru bond length of 2.8401 (7) Å. The dihedral angle between the planes of the cyclo­penta­dienyl ri...

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Detalles Bibliográficos
Autor principal: Zhu, Bolin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435588/
https://www.ncbi.nlm.nih.gov/pubmed/22969461
http://dx.doi.org/10.1107/S1600536812033454
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author Zhu, Bolin
author_facet Zhu, Bolin
author_sort Zhu, Bolin
collection PubMed
description The title compound, [Ru(2)(C(22)H(34)Si(2))(CO)(4)], contains two Ru(I) atoms linked by a bridging (η(5)-(t)BuC(5)H(2))(2)(SiMe(2))(2) ligand ((t)Bu is a tert-butyl and Me is a methyl group) with an Ru—Ru bond length of 2.8401 (7) Å. The dihedral angle between the planes of the cyclo­penta­dienyl rings of the ligand is 123.13 (19)°. The four terminal carbonyl ligands are bound in a symmetrical and staggered array. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds, forming inversion dimers.
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spelling pubmed-34355882012-09-11 [μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)] Zhu, Bolin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(2)(C(22)H(34)Si(2))(CO)(4)], contains two Ru(I) atoms linked by a bridging (η(5)-(t)BuC(5)H(2))(2)(SiMe(2))(2) ligand ((t)Bu is a tert-butyl and Me is a methyl group) with an Ru—Ru bond length of 2.8401 (7) Å. The dihedral angle between the planes of the cyclo­penta­dienyl rings of the ligand is 123.13 (19)°. The four terminal carbonyl ligands are bound in a symmetrical and staggered array. In the crystal, mol­ecules are linked via pairs of C—H⋯O hydrogen bonds, forming inversion dimers. International Union of Crystallography 2012-08-11 /pmc/articles/PMC3435588/ /pubmed/22969461 http://dx.doi.org/10.1107/S1600536812033454 Text en © Bolin Zhu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Bolin
[μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)]
title [μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)]
title_full [μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)]
title_fullStr [μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)]
title_full_unstemmed [μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)]
title_short [μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-Di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(I)]
title_sort [μ-(3,4,5,6,7-η:1,9,10,11,12)-5,11-di-tert-butyl-2,2,8,8-tetra­methyl-2,8-disila­tricyclo­[7.3.0.0(3,7)]dodeca­tetra­enedi­yl]bis­[dicarbonyl­ruthenium(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435588/
https://www.ncbi.nlm.nih.gov/pubmed/22969461
http://dx.doi.org/10.1107/S1600536812033454
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