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Highly enantioselective access to cannabinoid-type tricyles by organocatalytic Diels–Alder reactions

After prosperous domino reactions towards benzopyrans, the products were used as the starting material in Lewis acid catalyzed and organocatalytic Diels–Alder reactions to build up a tricyclic system. Herein, an asymmetric induction up to 96% enantiomeric excess was obtained by the use of imidazolid...

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Detalles Bibliográficos
Autores principales: Bräse, Stefan, Volz, Nicole, Gläser, Franziska, Nieger, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3458765/
https://www.ncbi.nlm.nih.gov/pubmed/23019475
http://dx.doi.org/10.3762/bjoc.8.160