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The crystal structure of the Dess–Martin periodinane

We report the elusive X-ray structure of the Dess–Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.

Detalles Bibliográficos
Autores principales: Schröckeneder, Albert, Stichnoth, Desiree, Mayer, Peter, Trauner, Dirk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3458777/
https://www.ncbi.nlm.nih.gov/pubmed/23019487
http://dx.doi.org/10.3762/bjoc.8.172