Cargando…
The crystal structure of the Dess–Martin periodinane
We report the elusive X-ray structure of the Dess–Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3458777/ https://www.ncbi.nlm.nih.gov/pubmed/23019487 http://dx.doi.org/10.3762/bjoc.8.172 |
_version_ | 1782244700708667392 |
---|---|
author | Schröckeneder, Albert Stichnoth, Desiree Mayer, Peter Trauner, Dirk |
author_facet | Schröckeneder, Albert Stichnoth, Desiree Mayer, Peter Trauner, Dirk |
author_sort | Schröckeneder, Albert |
collection | PubMed |
description | We report the elusive X-ray structure of the Dess–Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds. |
format | Online Article Text |
id | pubmed-3458777 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-34587772012-09-27 The crystal structure of the Dess–Martin periodinane Schröckeneder, Albert Stichnoth, Desiree Mayer, Peter Trauner, Dirk Beilstein J Org Chem Full Research Paper We report the elusive X-ray structure of the Dess–Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds. Beilstein-Institut 2012-09-12 /pmc/articles/PMC3458777/ /pubmed/23019487 http://dx.doi.org/10.3762/bjoc.8.172 Text en Copyright © 2012, Schröckeneder et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
spellingShingle | Full Research Paper Schröckeneder, Albert Stichnoth, Desiree Mayer, Peter Trauner, Dirk The crystal structure of the Dess–Martin periodinane |
title | The crystal structure of the Dess–Martin periodinane |
title_full | The crystal structure of the Dess–Martin periodinane |
title_fullStr | The crystal structure of the Dess–Martin periodinane |
title_full_unstemmed | The crystal structure of the Dess–Martin periodinane |
title_short | The crystal structure of the Dess–Martin periodinane |
title_sort | crystal structure of the dess–martin periodinane |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3458777/ https://www.ncbi.nlm.nih.gov/pubmed/23019487 http://dx.doi.org/10.3762/bjoc.8.172 |
work_keys_str_mv | AT schrockenederalbert thecrystalstructureofthedessmartinperiodinane AT stichnothdesiree thecrystalstructureofthedessmartinperiodinane AT mayerpeter thecrystalstructureofthedessmartinperiodinane AT traunerdirk thecrystalstructureofthedessmartinperiodinane AT schrockenederalbert crystalstructureofthedessmartinperiodinane AT stichnothdesiree crystalstructureofthedessmartinperiodinane AT mayerpeter crystalstructureofthedessmartinperiodinane AT traunerdirk crystalstructureofthedessmartinperiodinane |