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Phosphaalkenylidene bridged ferrocenes

The lithiation of ferrocenylphosphane Fc-PH(2) (Fc = –C(5)H(4)FeC(5)H(5)) has been reinvestigated and both Fc-PHLi and Fc-PLi(2) have been identified by NMR-spectroscopy. The lithiated phosphanides have been converted to the corresponding mono and bis(silylated) species the latter of which gave synt...

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Detalles Bibliográficos
Autores principales: Orthaber, Andreas, Herber, Rolfe H., Pietschnig, Rudolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier Sequoia 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3480635/
https://www.ncbi.nlm.nih.gov/pubmed/23162166
http://dx.doi.org/10.1016/j.jorganchem.2012.08.020