Synthesis of conformationally restricted glutamate and glutamine derivatives from carbonylation of orthopalladated phenylglycine derivatives

A new method for the regioselective synthesis of 2-alkoxycarbonyl- and 2-(aminocarbonyl)phenylglycinate methyl esters has been developed. The reaction of the orthopalladated complex [Pd(μ-Cl)(C(6)H(4)(CH(CO(2)Me)NMe(2))-2)](2) (1) with nucleophiles HNu under a CO atmosphere results in the selective...

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Detalles Bibliográficos
Autores principales: Urriolabeitia, Esteban P, Laga, Eduardo, Cativiela, Carlos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3510988/
https://www.ncbi.nlm.nih.gov/pubmed/23209488
http://dx.doi.org/10.3762/bjoc.8.179

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3510988/
https://www.ncbi.nlm.nih.gov/pubmed/23209488
http://dx.doi.org/10.3762/bjoc.8.179

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