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A new approach toward the total synthesis of (+)-batzellaside B

A new synthetic approach to (+)-batzellaside B from naturally abundant L-pyroglutamic acid is presented in this article. The key synthetic step involves Sharpless asymmetric dihydroxylation of an olefinic substrate functionalized with an acetoxy group to introduce two chiral centres diastereoselecti...

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Detalles Bibliográficos
Autores principales: Wierzejska, Jolanta, Motogoe, Shin-ichi, Makino, Yuto, Sengoku, Tetsuya, Takahashi, Masaki, Yoda, Hidemi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511019/
https://www.ncbi.nlm.nih.gov/pubmed/23209519
http://dx.doi.org/10.3762/bjoc.8.210