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Determination of the relative configuration of tropinone and granatanone aldols by using TBDMS ethers

The relative configurations of tert-butyldimethylsilyl (TBDMS) ethers of all four diastereomers of the aldols of tropinone (8-methyl-8-azabicyclo[3.2.1]octan-3-one), as well as of granatanone (9-methyl-9-azabicyclo[3.3.1]nonan-3-one), were determined from NMR data, and from the observed interconvers...

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Detalles Bibliográficos
Autores principales: Lazny, Ryszard, Nodzewska, Aneta, Sidorowicz, Katarzyna, Kalicki, Przemyslaw
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511025/
https://www.ncbi.nlm.nih.gov/pubmed/23209525
http://dx.doi.org/10.3762/bjoc.8.216