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Influence of intramolecular hydrogen bonds on the binding potential of methylated β-cyclodextrin derivatives

Various heptasubstituted derivatives of β-cyclodextrin (β-CD) bearing 1, 2 and 3 methyl substituents per glucose unit were synthesized by regioselective methods. Binding free energies and binding enthalpies of these hosts towards 4-tert-butylbenzoate and adamantane-1-carboxylate were determined by i...

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Detalles Bibliográficos
Autor principal: Wenz, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3511027/
https://www.ncbi.nlm.nih.gov/pubmed/23209527
http://dx.doi.org/10.3762/bjoc.8.218