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[Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate

The title salt, [Ru(Tp)(CH(5)N)(2)(PPh(3))]Cl·CH(2)Cl(2)·H(2)O [where Tp is (C(3)H(3)N(2))(3)BH and PPH(3) is C(18)H(15)P], has the Ru(III) atom in an octa­hedral geometry; one of the Ru—N(Tp) bonds [2.135 (8) Å] is slightly longer than another two, owing to the trans influence of PPh(3) ligand. N—H...

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Detalles Bibliográficos
Autores principales: Lin, Yi-Dong, Chang, Chin-Pei, Huang, Quan-Sheng, Lo, Yih-Hsing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515107/
https://www.ncbi.nlm.nih.gov/pubmed/23284334
http://dx.doi.org/10.1107/S1600536812042110