[Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate

The title salt, [Ru(Tp)(CH(5)N)(2)(PPh(3))]Cl·CH(2)Cl(2)·H(2)O [where Tp is (C(3)H(3)N(2))(3)BH and PPH(3) is C(18)H(15)P], has the Ru(III) atom in an octa­hedral geometry; one of the Ru—N(Tp) bonds [2.135 (8) Å] is slightly longer than another two, owing to the trans influence of PPh(3) ligand. N—H...

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Autores principales: Lin, Yi-Dong, Chang, Chin-Pei, Huang, Quan-Sheng, Lo, Yih-Hsing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515107/
https://www.ncbi.nlm.nih.gov/pubmed/23284334
http://dx.doi.org/10.1107/S1600536812042110
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author Lin, Yi-Dong
Chang, Chin-Pei
Huang, Quan-Sheng
Lo, Yih-Hsing
author_facet Lin, Yi-Dong
Chang, Chin-Pei
Huang, Quan-Sheng
Lo, Yih-Hsing
author_sort Lin, Yi-Dong
collection PubMed
description The title salt, [Ru(Tp)(CH(5)N)(2)(PPh(3))]Cl·CH(2)Cl(2)·H(2)O [where Tp is (C(3)H(3)N(2))(3)BH and PPH(3) is C(18)H(15)P], has the Ru(III) atom in an octa­hedral geometry; one of the Ru—N(Tp) bonds [2.135 (8) Å] is slightly longer than another two, owing to the trans influence of PPh(3) ligand. N—H⋯Cl and O—H⋯Cl hydrogen bonding leads to the formation of layers parallel to (100).
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spelling pubmed-35151072013-01-02 [Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate Lin, Yi-Dong Chang, Chin-Pei Huang, Quan-Sheng Lo, Yih-Hsing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, [Ru(Tp)(CH(5)N)(2)(PPh(3))]Cl·CH(2)Cl(2)·H(2)O [where Tp is (C(3)H(3)N(2))(3)BH and PPH(3) is C(18)H(15)P], has the Ru(III) atom in an octa­hedral geometry; one of the Ru—N(Tp) bonds [2.135 (8) Å] is slightly longer than another two, owing to the trans influence of PPh(3) ligand. N—H⋯Cl and O—H⋯Cl hydrogen bonding leads to the formation of layers parallel to (100). International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515107/ /pubmed/23284334 http://dx.doi.org/10.1107/S1600536812042110 Text en © Lin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Yi-Dong
Chang, Chin-Pei
Huang, Quan-Sheng
Lo, Yih-Hsing
[Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate
title [Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate
title_full [Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate
title_fullStr [Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate
title_full_unstemmed [Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate
title_short [Hydridotris(pyrazol-1-yl-κN (2))borato]bis­(methyl­amino-κN)(triphenyl­phos­phine-κP)ruthenium(II) chloride dichloro­methane solvate monohydrate
title_sort [hydridotris(pyrazol-1-yl-κn (2))borato]bis­(methyl­amino-κn)(triphenyl­phos­phine-κp)ruthenium(ii) chloride dichloro­methane solvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515107/
https://www.ncbi.nlm.nih.gov/pubmed/23284334
http://dx.doi.org/10.1107/S1600536812042110
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AT huangquansheng hydridotrispyrazol1ylkn2boratobismethylaminokntriphenylphosphinekprutheniumiichloridedichloromethanesolvatemonohydrate
AT loyihhsing hydridotrispyrazol1ylkn2boratobismethylaminokntriphenylphosphinekprutheniumiichloridedichloromethanesolvatemonohydrate

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