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Di-μ-carbonyl-bis­[bis­(triphenyl­phos­phane)rhodium(0)](Rh—Rh) acetone disolvate

The dirhodium complex, [Rh(2)(C(18)H(15)P)(4)(CO)(2)]·2(CH(3))(2)CO, has crystallographic twofold symmetry and the Rh—Rh distance is 2.6266 (8) Å. The four atoms proximate to each Rh atom [Rh—P = 2.3222 (7) and 2.3283 (8) Å, and Rh—C = 1.961 (3) and 2.045 (3) Å] form a distorted tetra­hedron with la...

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Detalles Bibliográficos
Autores principales: Gueorguieva, Petia G., Laneman, Scott A., Stanley, George G., Fronczek, Frank R., Watkins, Steven F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515148/
https://www.ncbi.nlm.nih.gov/pubmed/23284375
http://dx.doi.org/10.1107/S1600536812043528