3,5-Dimethylpyrazolium 3,5-dinitrosalicylate
In the title molecular salt, C(5)H(9)N(2) (+)·C(7)H(3)N(2)O(7) (−), the roughly planar anion (r.m.s. deviation = 0.120 Å) has been deprotonated at the phenol group. An intramolecular O—H⋯O hydrogen bond in the anion generates an S(6) ring. In the crystal, the components are linked by cation-to-ani...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515222/ https://www.ncbi.nlm.nih.gov/pubmed/23284442 http://dx.doi.org/10.1107/S1600536812041906 |
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author | Wei, Shuaishuai Jin, Shouwen Hu, Zhaofeng Zhou, Yong Zhou, Yingping |
author_facet | Wei, Shuaishuai Jin, Shouwen Hu, Zhaofeng Zhou, Yong Zhou, Yingping |
author_sort | Wei, Shuaishuai |
collection | PubMed |
description | In the title molecular salt, C(5)H(9)N(2) (+)·C(7)H(3)N(2)O(7) (−), the roughly planar anion (r.m.s. deviation = 0.120 Å) has been deprotonated at the phenol group. An intramolecular O—H⋯O hydrogen bond in the anion generates an S(6) ring. In the crystal, the components are linked by cation-to-anion N—H⋯O and N—H⋯(O,O) hydrogen bonds, generating [010] double chains. Weak C—H⋯O interactions consolidate the packing. |
format | Online Article Text |
id | pubmed-3515222 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35152222013-01-02 3,5-Dimethylpyrazolium 3,5-dinitrosalicylate Wei, Shuaishuai Jin, Shouwen Hu, Zhaofeng Zhou, Yong Zhou, Yingping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(5)H(9)N(2) (+)·C(7)H(3)N(2)O(7) (−), the roughly planar anion (r.m.s. deviation = 0.120 Å) has been deprotonated at the phenol group. An intramolecular O—H⋯O hydrogen bond in the anion generates an S(6) ring. In the crystal, the components are linked by cation-to-anion N—H⋯O and N—H⋯(O,O) hydrogen bonds, generating [010] double chains. Weak C—H⋯O interactions consolidate the packing. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515222/ /pubmed/23284442 http://dx.doi.org/10.1107/S1600536812041906 Text en © Wei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wei, Shuaishuai Jin, Shouwen Hu, Zhaofeng Zhou, Yong Zhou, Yingping 3,5-Dimethylpyrazolium 3,5-dinitrosalicylate |
title | 3,5-Dimethylpyrazolium 3,5-dinitrosalicylate |
title_full | 3,5-Dimethylpyrazolium 3,5-dinitrosalicylate |
title_fullStr | 3,5-Dimethylpyrazolium 3,5-dinitrosalicylate |
title_full_unstemmed | 3,5-Dimethylpyrazolium 3,5-dinitrosalicylate |
title_short | 3,5-Dimethylpyrazolium 3,5-dinitrosalicylate |
title_sort | 3,5-dimethylpyrazolium 3,5-dinitrosalicylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515222/ https://www.ncbi.nlm.nih.gov/pubmed/23284442 http://dx.doi.org/10.1107/S1600536812041906 |
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