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On the Preparation and Determination of Configurational Stability of Chiral Thio- and Bromo[D(1)]methyllithiums
[Image: see text] Thio- and bromo[D(1)]methyllithiums (ee 99%) were generated from the respective stannanes by tin–lithium exchange at temperatures ranging from 0 to −95 °C. Thio[D(1)]methyllithiums 6 were found to be microscopically configurationally labile on the time scale of the thiophosphate-α-...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3557930/ https://www.ncbi.nlm.nih.gov/pubmed/23106613 http://dx.doi.org/10.1021/jo301441g |