Fingerprints of Adiabatic versus Diabatic Vibronic Dynamics in the Asymmetry of Photoelectron Momentum Distributions

[Image: see text] When the Born–Oppenheimer approximation is valid, electrons adiabatically follow the nuclear motion in molecules. For strong nonadiabatic coupling between electronic states, one encounters a diabatic motion where the electrons remain local and do not adapt to molecular geometry cha...

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Detalles Bibliográficos
Autores principales: Falge, Mirjam, Engel, Volker, Gräfe, Stefanie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2012
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3560423/
https://www.ncbi.nlm.nih.gov/pubmed/23378888
http://dx.doi.org/10.1021/jz3009826

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3560423/
https://www.ncbi.nlm.nih.gov/pubmed/23378888
http://dx.doi.org/10.1021/jz3009826

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