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Fingerprints of Adiabatic versus Diabatic Vibronic Dynamics in the Asymmetry of Photoelectron Momentum Distributions
[Image: see text] When the Born–Oppenheimer approximation is valid, electrons adiabatically follow the nuclear motion in molecules. For strong nonadiabatic coupling between electronic states, one encounters a diabatic motion where the electrons remain local and do not adapt to molecular geometry cha...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3560423/ https://www.ncbi.nlm.nih.gov/pubmed/23378888 http://dx.doi.org/10.1021/jz3009826 |