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Efficient synthesis of phenylene-ethynylene rods and their use as rigid spacers in divalent inhibitors
The synthesis of phenylene-ethynylene rods and their use as rigid spacers is described. Alternation of a Sonogashira reaction and silyl group cleavage was used to obtain rigid spacers with even and odd numbers of phenylene units. Preliminary applications of these rods in divalent systems are shown....
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3566787/ https://www.ncbi.nlm.nih.gov/pubmed/23400701 http://dx.doi.org/10.3762/bjoc.9.25 |