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A spectroscopic and computational study of Al(III) complexes in cryolite melts: Effect of cation nature
Lithium, sodium and potassium cryolite melts are probed by Raman spectroscopy in a wide range of the melt composition. The experimental data demonstrate a slight red shift of main peaks and a decrease of their half-widths in the row Li(+), Na(+), K(+). Quantum chemical modelling of the systems is pe...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
North Holland Publishing
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3568921/ https://www.ncbi.nlm.nih.gov/pubmed/23408115 http://dx.doi.org/10.1016/j.chemphys.2012.11.006 |