Cargando…

A spectroscopic and computational study of Al(III) complexes in cryolite melts: Effect of cation nature

Lithium, sodium and potassium cryolite melts are probed by Raman spectroscopy in a wide range of the melt composition. The experimental data demonstrate a slight red shift of main peaks and a decrease of their half-widths in the row Li(+), Na(+), K(+). Quantum chemical modelling of the systems is pe...

Descripción completa

Detalles Bibliográficos
Autores principales: Nazmutdinov, Renat R., Zinkicheva, Tamara T., Vassiliev, Sergey Yu., Glukhov, Dmitrii V., Tsirlina, Galina A., Probst, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: North Holland Publishing 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3568921/
https://www.ncbi.nlm.nih.gov/pubmed/23408115
http://dx.doi.org/10.1016/j.chemphys.2012.11.006