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Preparation of Carboxylato-Coordinated Titanium Alkoxides from Carboxylic Anhydrides: Alkoxido Group Transfer from Metal Atom to Carbonyl Group
Reaction of titanium(IV) isopropoxide, Ti(OiPr)(4), with an equimolar amount of phthalic anhydride resulted in the transfer of an isopropoxido group from the metal atom to one carbonyl group of the anhydride and coordination of the thus formed monoester to the titanium atom. One monoester ligand in...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3573866/ https://www.ncbi.nlm.nih.gov/pubmed/23549605 http://dx.doi.org/10.1002/ejic.201200296 |