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Preparation of Carboxylato-Coordinated Titanium Alkoxides from Carboxylic Anhydrides: Alkoxido Group Transfer from Metal Atom to Carbonyl Group

Reaction of titanium(IV) isopropoxide, Ti(OiPr)(4), with an equimolar amount of phthalic anhydride resulted in the transfer of an isopropoxido group from the metal atom to one carbonyl group of the anhydride and coordination of the thus formed monoester to the titanium atom. One monoester ligand in...

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Detalles Bibliográficos
Autores principales: Czakler, Matthias, Artner, Christine, Schubert, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3573866/
https://www.ncbi.nlm.nih.gov/pubmed/23549605
http://dx.doi.org/10.1002/ejic.201200296