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Biferrocene-Based Diphosphine Ligands: Synthesis and Application of Walphos Analogues in Asymmetric Hydrogenations

[Image: see text] A total of four biferrocene-based Walphos-type ligands have been synthesized, structurally characterized, and tested in the rhodium-, ruthenium- and iridium-catalyzed hydrogenation of alkenes and ketones. Negishi coupling conditions allowed the biferrocene backbone of these diphosp...

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Detalles Bibliográficos
Autores principales: Zirakzadeh, Afrooz, Groß, Manuela A., Wang, Yaping, Mereiter, Kurt, Spindler, Felix, Weissensteiner, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3584622/
https://www.ncbi.nlm.nih.gov/pubmed/23457421
http://dx.doi.org/10.1021/om3012147