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The mixed-valent copper thiolate complex hexakis{μ(3)-2-[(1,3-dimethylimidazolidene)amino]benzenethiolato}dicopper(II)tetracopper(I) bis(hexafluoridophosphate) acetonitrile disolvate dichloromethane disolvate
The molecular structure of the title compound, [Cu(4) (I)Cu(2) (II)(C(11)H(14)N(3)S)(6)](PF(6))(2)·2CH(3)CN·2CH(2)Cl(2), shows a mixed-valent copper(I/II) thiolate complex with a distorted tetrahedral coordination of the Cu(I) and Cu(II) cations by one guanidine N atom and three S atoms each. Cha...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588332/ https://www.ncbi.nlm.nih.gov/pubmed/23476349 http://dx.doi.org/10.1107/S1600536812050428 |