Cargando…

The mixed-valent copper thiolate complex hexakis{μ(3)-2-[(1,3-dimethylimidazolidene)amino]benzenethiolato}dicopper(II)tetracopper(I) bis(hexafluoridophosphate) acetonitrile disolvate dichloromethane disolvate

The molecular structure of the title compound, [Cu(4) (I)Cu(2) (II)(C(11)H(14)N(3)S)(6)](PF(6))(2)·2CH(3)CN·2CH(2)Cl(2), shows a mixed-valent copper(I/II) thiolate complex with a distorted tetrahedral coordination of the Cu(I) and Cu(II) cations by one guanidine N atom and three S atoms each. Cha...

Descripción completa

Detalles Bibliográficos
Autores principales:	Neuba, Adam, Flörke, Ulrich, Henkel, Gerald
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2012
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588332/ https://www.ncbi.nlm.nih.gov/pubmed/23476349 http://dx.doi.org/10.1107/S1600536812050428

Ejemplares similares

Tetrakis(triphenylarsine)copper(I) hexafluoridophosphate
por: Kern, Thomas, et al.
Publicado: (2007)

Hexakis(1H-imidazole-κN (3))cobalt(III) tris(hexafluoridophosphate) hexahydrate
por: Surdykowski, Andrzej, et al.
Publicado: (2009)

[1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate
por: Hou, Jian-Guo
Publicado: (2011)

(4′-Ethynyl-2,2′:6′,2′′-terpyridine)(2,2′:6′,2′′-terpyridine)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate
por: Chen, Weizhong, et al.
Publicado: (2013)

Bis[(diphenylphosphanylmethyl)diphenylphosphane sulfide-κ(2) P,S]copper(I) hexafluoridophosphate
por: Zhang, Jing-Jing, et al.
Publicado: (2012)

Bis[N,N-bis(diphenylphosphanyl)pentylamine-κ(2) P,P′]platinum(II) bis(hexafluoridophosphate) dichloromethane disolvate
por: Engelbrecht, Ilana, et al.
Publicado: (2010)

Chlorido[1-(diphenylphosphanyl)cobaltocenium]gold(I) hexafluoridophosphate
por: Wu, Xiang-Hua
Publicado: (2011)

Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate
por: Seo, Daniel M., et al.
Publicado: (2011)

1,1′-(p-Phenylenedimethylene)dipyridinium bis(hexafluoridophosphate)
por: Abdul Rahim, Munirah Sufiyah, et al.
Publicado: (2010)

Tris(pyridin-2-ylmethanol)nickel(II) hexafluoridophosphate trifluoroacetate
por: Hamaguchi, Tomohiko, et al.
Publicado: (2011)

Tricarbonylbis(triphenylphosphane-κP)iridium(I) hexafluoridophosphate methanol monosolvate
por: Engelbrecht, Ilana, et al.
Publicado: (2012)

trans-Bis(μ-benzenethiolato-κ(2) S:S)bis[chlorido(triphenylphosphane-κP)palladium(II)] chloroform disolvate
por: Avila-Sorrosa, Alcives, et al.
Publicado: (2013)

Bis[(1-vinyl-1H-imidazol-2-yl-κN (3))methanamine-κN]copper(II) bis(hexafluoridophosphate)
por: Schiller, Alexander, et al.
Publicado: (2011)

Bis(phenanthridinium) hexachloridoplatinate(IV) dimethyl sulfoxide disolvate
por: Karaca, Selvi, et al.
Publicado: (2009)

4-[(2′-Cyanobiphenyl-4-yl)methyl]morpholin-4-ium hexafluoridophosphate
por: Xue, Hua Yu, et al.
Publicado: (2012)

Potassium bis[bis(1-benzyl-3-methylimidazolium)silver(I)] tris(hexafluoridophosphate)
por: Haque, Rosenani A., et al.
Publicado: (2010)

Tris(2,2′-bipyridine-κ(2) N,N′)cobalt(II) bis(hexafluoridophosphate)
por: Menteş, Ayfer, et al.
Publicado: (2012)

trans-(Pyrimidine-2-thiolato-κ(2) N,S)[tris(2-aminoethyl)amine-κ(4) N,N′,N′′,N′′′]cobalt(III) chloride hexafluoridophosphate
por: Fujihara, Keisuke, et al.
Publicado: (2009)

(2-Aminoethanethiolato-κ(2) N,S)bis[1,2-bis(diphenylphosphanyl)ethane-κ(2) P,P′]ruthenium(II) hexafluoridophosphate
por: Igashira-Kamiyama, Asako, et al.
Publicado: (2012)

Bis{1-[2-(diphenylphosphino)ethyl]-3-ethylimidazol-2-ylidene}palladium(II) bis(hexafluoridophosphate) acetonitrile 2.85-solvate
por: Aziza, A. Ahmida, et al.
Publicado: (2010)

Bis(benzenethiolato)(2,2′-biquinoline)zinc(II)
por: Monroe, Thomas Blake, et al.
Publicado: (2009)

Rhodamine 6G hexachloridostannate(IV) acetonitrile disolvate
por: Venkatraman, Ramaiyer, et al.
Publicado: (2007)

Hexa-μ(2)-chlorido-μ(4)-oxido-tetrakis[(morpholine-κN)copper(II)] methanol disolvate
por: Gubina, Kateryna, et al.
Publicado: (2014)

Tris(tetrabutylammonium) hexakis(tert-butanethiolato-κS)hepta-μ(3)-chlorido-μ(3)-sulfido-hexamolybdate dihydrate
por: Petrov, Pavel A., et al.
Publicado: (2012)

Bis(1-benzyl-3-methylimidazolium-κC (2))mercury(II) bis(hexafluoridophosphate)
por: Haque, Rosenani A., et al.
Publicado: (2011)

2,4-Bis[(3-allylimidazolium-1-yl)methyl]mesitylene bis(hexafluoridophosphate)
por: Haque, Rosenani A., et al.
Publicado: (2011)

5,11,17,23,29,35-Hexa-tert-butyl-37,38,39,40,41,42-hexakis(ethoxycarbonylmethoxy)calix[6]arene acetonitrile disolvate
por: Pojarová, Michaela, et al.
Publicado: (2012)

[2,6-Bis(5-chloropyrimidin-2-yl-κN)pyridine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) acetonitrile disolvate
por: Medlycott, Elaine A., et al.
Publicado: (2008)

Hexakis(μ(3)-1-methylthiourea-κ(3) S:S:S)hexakis[iodidocopper(I)]
por: Ahmad, Saeed, et al.
Publicado: (2012)

1,3-Bis[(3-allylimidazol-3-ium-1-yl)methyl]benzene bis(hexafluoridophosphate)
por: Haque, Rosenani A., et al.
Publicado: (2010)

Bis{1,4-bis[(3-butylimidazolium-1-yl)methyl]benzene}silver(I) bis(hexafluoridophosphate)
por: Haque, Rosenani A., et al.
Publicado: (2010)

(η(5)-Cyclopentadienyl)(η(6)-1,2-dipyrrolidin-1-ylbenzene)iron(II) hexafluoridophosphate
por: Jenkins, Hilary A., et al.
Publicado: (2009)

{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3) P,P′,P′′}chloridopalladium(II) hexafluoridophosphate
por: Vorce, Paul R., et al.
Publicado: (2009)

Bis(2,2′-bipyridine)(5-isothiocyanato-1,10-phenanthroline)ruthenium(II) bis(hexafluoridophosphate) acetonitrile solvate
por: Nag, Samik, et al.
Publicado: (2009)

{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3) P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate
por: Heston, Scott A., et al.
Publicado: (2009)

9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate)
por: Guo, Li-Hui, et al.
Publicado: (2007)

Chloridotetrapyridinecopper(II) dicyanamidate pyridine disolvate
por: Wöhlert, Susanne, et al.
Publicado: (2011)

Bis(μ-hexadecanoato-κ(2) O:O)bis[(2,2′-bipyridine-κ(2) N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate
por: Che Mat, Ahmad Nazeer, et al.
Publicado: (2011)

Hexakis(3-chloro-2-methylanilinium) cyclohexaphosphate dihydrate
por: Bel Haj Salah, Raoudha, et al.
Publicado: (2013)

{3,3′-Bis[(anthracen-9-yl)methyl]-1,1′-[(ethane-1,2-diyldioxy)bis(ethane-1,2-diyl)]bis(imidazol-2-ylidene)}mercury(II) bis(hexafluoridophosphate) acetonitrile disolvate
por: Wang, Jun-Wen, et al.
Publicado: (2012)

Cannot write session to /tmp/vufind_sessions/sess_pj0aslvv8undeppne7j9n5km5d