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Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetrakis(pentafluorophenyl)borate
In the title molecular salt, C(36)H(30)NP(2) (+)·C(24)BF(20) (−), the P—N bond lengths in the cation are equal [1.573 (2) and 1.572 (2) Å], indicating a resonance structure and the P—N—P bond angle is 144.79 (12)°. In the crystal, weak C—H⋯F interactions link the cations and the anions....
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588361/ https://www.ncbi.nlm.nih.gov/pubmed/23476468 http://dx.doi.org/10.1107/S1600536812049914 |