Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate

In the title molecular salt, C(36)H(30)NP(2) (+)·C(24)BF(20) (−), the P—N bond lengths in the cation are equal [1.573 (2) and 1.572 (2) Å], indicating a resonance structure and the P—N—P bond angle is 144.79 (12)°. In the crystal, weak C—H⋯F interactions link the cations and the anions....

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Detalles Bibliográficos
Autores principales: Vanýsek, Petr, Zheng, Chong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588361/
https://www.ncbi.nlm.nih.gov/pubmed/23476468
http://dx.doi.org/10.1107/S1600536812049914
Descripción
Sumario:In the title molecular salt, C(36)H(30)NP(2) (+)·C(24)BF(20) (−), the P—N bond lengths in the cation are equal [1.573 (2) and 1.572 (2) Å], indicating a resonance structure and the P—N—P bond angle is 144.79 (12)°. In the crystal, weak C—H⋯F interactions link the cations and the anions.

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