Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate

In the title molecular salt, C(36)H(30)NP(2) (+)·C(24)BF(20) (−), the P—N bond lengths in the cation are equal [1.573 (2) and 1.572 (2) Å], indicating a resonance structure and the P—N—P bond angle is 144.79 (12)°. In the crystal, weak C—H⋯F interactions link the cations and the anions....

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Detalles Bibliográficos
Autores principales: Vanýsek, Petr, Zheng, Chong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588361/
https://www.ncbi.nlm.nih.gov/pubmed/23476468
http://dx.doi.org/10.1107/S1600536812049914
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author Vanýsek, Petr
Zheng, Chong
author_facet Vanýsek, Petr
Zheng, Chong
author_sort Vanýsek, Petr
collection PubMed
description In the title molecular salt, C(36)H(30)NP(2) (+)·C(24)BF(20) (−), the P—N bond lengths in the cation are equal [1.573 (2) and 1.572 (2) Å], indicating a resonance structure and the P—N—P bond angle is 144.79 (12)°. In the crystal, weak C—H⋯F interactions link the cations and the anions.
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spelling pubmed-35883612013-03-08 Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate Vanýsek, Petr Zheng, Chong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(36)H(30)NP(2) (+)·C(24)BF(20) (−), the P—N bond lengths in the cation are equal [1.573 (2) and 1.572 (2) Å], indicating a resonance structure and the P—N—P bond angle is 144.79 (12)°. In the crystal, weak C—H⋯F interactions link the cations and the anions. International Union of Crystallography 2012-12-15 /pmc/articles/PMC3588361/ /pubmed/23476468 http://dx.doi.org/10.1107/S1600536812049914 Text en © Vanýsek and Zheng 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vanýsek, Petr
Zheng, Chong
Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate
title Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate
title_full Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate
title_fullStr Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate
title_full_unstemmed Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate
title_short Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate
title_sort triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra­kis­(penta­fluoro­phen­yl)borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588361/
https://www.ncbi.nlm.nih.gov/pubmed/23476468
http://dx.doi.org/10.1107/S1600536812049914
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