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2,2-Dibenzylhydrazin-1-ium chloride
In the title salt, C(14)H(17)N(2) (+)·Cl(−), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N—H⋯Cl hydrogen bonds, which lead to a supramolecular undulat...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588411/ https://www.ncbi.nlm.nih.gov/pubmed/23476568 http://dx.doi.org/10.1107/S1600536813003966 |
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author | Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. |
author_facet | Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. |
author_sort | Tayamon, Shahedeh |
collection | PubMed |
description | In the title salt, C(14)H(17)N(2) (+)·Cl(−), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N—H⋯Cl hydrogen bonds, which lead to a supramolecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}(2) synthons. The chains are connected into layers in the ab plane by C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3588411 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35884112013-03-08 2,2-Dibenzylhydrazin-1-ium chloride Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(14)H(17)N(2) (+)·Cl(−), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N—H⋯Cl hydrogen bonds, which lead to a supramolecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}(2) synthons. The chains are connected into layers in the ab plane by C—H⋯π interactions. International Union of Crystallography 2013-02-16 /pmc/articles/PMC3588411/ /pubmed/23476568 http://dx.doi.org/10.1107/S1600536813003966 Text en © Tayamon et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. 2,2-Dibenzylhydrazin-1-ium chloride |
title | 2,2-Dibenzylhydrazin-1-ium chloride |
title_full | 2,2-Dibenzylhydrazin-1-ium chloride |
title_fullStr | 2,2-Dibenzylhydrazin-1-ium chloride |
title_full_unstemmed | 2,2-Dibenzylhydrazin-1-ium chloride |
title_short | 2,2-Dibenzylhydrazin-1-ium chloride |
title_sort | 2,2-dibenzylhydrazin-1-ium chloride |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588411/ https://www.ncbi.nlm.nih.gov/pubmed/23476568 http://dx.doi.org/10.1107/S1600536813003966 |
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