2,2-Dibenzyl­hydrazin-1-ium chloride

In the title salt, C(14)H(17)N(2) (+)·Cl(−), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N—H⋯Cl hydrogen bonds, which lead to a supra­molecular undulat...

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Autores principales: Tayamon, Shahedeh, Ravoof, Thahira Begum S. A., Tahir, Mohamed Ibrahim Mohamed, Crouse, Karen A., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588411/
https://www.ncbi.nlm.nih.gov/pubmed/23476568
http://dx.doi.org/10.1107/S1600536813003966
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author Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_facet Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_sort Tayamon, Shahedeh
collection PubMed
description In the title salt, C(14)H(17)N(2) (+)·Cl(−), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N—H⋯Cl hydrogen bonds, which lead to a supra­molecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}(2) synthons. The chains are connected into layers in the ab plane by C—H⋯π inter­actions.
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spelling pubmed-35884112013-03-08 2,2-Dibenzyl­hydrazin-1-ium chloride Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(14)H(17)N(2) (+)·Cl(−), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N—H⋯Cl hydrogen bonds, which lead to a supra­molecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}(2) synthons. The chains are connected into layers in the ab plane by C—H⋯π inter­actions. International Union of Crystallography 2013-02-16 /pmc/articles/PMC3588411/ /pubmed/23476568 http://dx.doi.org/10.1107/S1600536813003966 Text en © Tayamon et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
2,2-Dibenzyl­hydrazin-1-ium chloride
title 2,2-Dibenzyl­hydrazin-1-ium chloride
title_full 2,2-Dibenzyl­hydrazin-1-ium chloride
title_fullStr 2,2-Dibenzyl­hydrazin-1-ium chloride
title_full_unstemmed 2,2-Dibenzyl­hydrazin-1-ium chloride
title_short 2,2-Dibenzyl­hydrazin-1-ium chloride
title_sort 2,2-dibenzyl­hydrazin-1-ium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588411/
https://www.ncbi.nlm.nih.gov/pubmed/23476568
http://dx.doi.org/10.1107/S1600536813003966
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AT tahirmohamedibrahimmohamed 22dibenzylhydrazin1iumchloride
AT crousekarena 22dibenzylhydrazin1iumchloride
AT tiekinkedwardrt 22dibenzylhydrazin1iumchloride

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