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[(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate

In the title complex, [Ru(C(19)H(25)N(2)O(2))H(C(44)H(32)P(2))]·C(6)H(6), the Ru(II) ion is in a distorted octa­hedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H—Ru—N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, t...

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Detalles Bibliográficos
Autores principales: Abdur-Rashid, Kamaluddin, Lough, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588743/
https://www.ncbi.nlm.nih.gov/pubmed/23468708
http://dx.doi.org/10.1107/S1600536812046065