[(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate

In the title complex, [Ru(C(19)H(25)N(2)O(2))H(C(44)H(32)P(2))]·C(6)H(6), the Ru(II) ion is in a distorted octa­hedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H—Ru—N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, t...

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Detalles Bibliográficos
Autores principales: Abdur-Rashid, Kamaluddin, Lough, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588743/
https://www.ncbi.nlm.nih.gov/pubmed/23468708
http://dx.doi.org/10.1107/S1600536812046065
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author Abdur-Rashid, Kamaluddin
Lough, Alan J.
author_facet Abdur-Rashid, Kamaluddin
Lough, Alan J.
author_sort Abdur-Rashid, Kamaluddin
collection PubMed
description In the title complex, [Ru(C(19)H(25)N(2)O(2))H(C(44)H(32)P(2))]·C(6)H(6), the Ru(II) ion is in a distorted octa­hedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H—Ru—N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom.
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spelling pubmed-35887432013-03-06 [(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate Abdur-Rashid, Kamaluddin Lough, Alan J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ru(C(19)H(25)N(2)O(2))H(C(44)H(32)P(2))]·C(6)H(6), the Ru(II) ion is in a distorted octa­hedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H—Ru—N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom. International Union of Crystallography 2012-11-17 /pmc/articles/PMC3588743/ /pubmed/23468708 http://dx.doi.org/10.1107/S1600536812046065 Text en © Abdur-Rashid and Lough 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abdur-Rashid, Kamaluddin
Lough, Alan J.
[(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate
title [(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate
title_full [(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate
title_fullStr [(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate
title_full_unstemmed [(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate
title_short [(R)-2,2-Bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κC (1)}hydrido­ruthenium(II) benzene monosolvate
title_sort [(r)-2,2-bis(diphenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) p,p′]{2-[(2r)-1,2-diamino-1-(4-meth­oxy­phen­yl)-3-methyl­but­yl]-5-meth­oxy­phenyl-κc (1)}hydrido­ruthenium(ii) benzene monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588743/
https://www.ncbi.nlm.nih.gov/pubmed/23468708
http://dx.doi.org/10.1107/S1600536812046065
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AT loughalanj r22bisdiphenylphosphanyl11binaphthylk2pp22r12diamino14methoxyphenyl3methylbutyl5methoxyphenylkc1hydridorutheniumiibenzenemonosolvate

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