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[(R)-2,2-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ(2) P,P′]{2-[(2R)-1,2-diamino-1-(4-methoxyphenyl)-3-methylbutyl]-5-methoxyphenyl-κC (1)}hydridoruthenium(II) benzene monosolvate
In the title complex, [Ru(C(19)H(25)N(2)O(2))H(C(44)H(32)P(2))]·C(6)H(6), the Ru(II) ion is in a distorted octahedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H—Ru—N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, t...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588743/ https://www.ncbi.nlm.nih.gov/pubmed/23468708 http://dx.doi.org/10.1107/S1600536812046065 |