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[(Triethyl­ene­tetra­mine)copper(II)]-μ-cyanido-κ(2) N:C-[bis(cyanido-κC)copper(I)]

The title compound, [Cu(2)(CN)(3)(C(6)H(18)N(4))] or [Cu(trien)(CN)Cu(CN)(2)], where trien is triethyl­ene­tetra­mine, is a mixed-valence complex crystallizing as discrete mol­ecules, with Cu(I) and Cu(II) ions linked by a bridging cyanide group. The Cu(II) ion is in a square-pyramidal coordination...

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Detalles Bibliográficos
Autores principales: Corfield, Peter W. R., Grillo, Scott A., Umstott, Nancy S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588776/
https://www.ncbi.nlm.nih.gov/pubmed/23468741
http://dx.doi.org/10.1107/S1600536812047745