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μ-Carbonato-κ(4) O,O′:O′,O′′-bis­{[2′-(di-tert-butyl­phosphan­yl)biphenyl-2-yl-κ(2) P,C (1)]palladium(II)} dichloro­methane monosolvate

The title compound, [(μ(2)-CO(3)){Pd(P(t-C(4)H(9))(2)(C(12)H(8))}(2)]·CH(2)Cl(2), the first CO(3)-bridged palladium dimer complex reported to date, was obtained while preparing the Pd(0) complex with (2-biphen­yl)P((t)Bu)(2). In the crystal, each palladium dimer is accompanied by a dichloro­methane...

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Detalles Bibliográficos
Autores principales: Muller, Alfred, Holzapfel, Cedric W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588806/
https://www.ncbi.nlm.nih.gov/pubmed/23468771
http://dx.doi.org/10.1107/S1600536812048702